Fabrication of Three-Dimensional Flower-like Heterogeneous Fe₃O₄/Fe Particles with Tunable Chemical Composition and Microwave Absorption Performance

Abstract

Heterogeneous Fe₃O₄ and Fe composites are highly desirable for microwave absorption application because of their complementary electromagnetic (EM) properties. With three-dimensional (3D) Fe₂O₃ as a sacrificing template, we realize the construction of Fe₃O₄/Fe composites with tunable chemical composition, and more importantly, these composites inherit the unique 3D microstructure from their precursor. The change in chemical composition produces significant impacts on the EM functions of these composites. On the one hand, dielectric loss can be improved greatly through positive interfacial polarization and reach the peak when the mass contents of Fe₃O₄ and Fe are 72.1 and 27.9 wt %, respectively. On the other hand, high Fe content slightly pulls down magnetic loss in the low-frequency range but favors strong magnetic loss in the high-frequency range because of the breakthrough of Snoek's limitation. The attenuation constant reveals that dielectric loss dominates overall consumption of incident EM waves. As a result, the optimized composite, F-350 (the reduction of Fe₂O₃ is conducted at 350 °C), shows the best microwave absorption performance, whose strongest reflection loss is -56.0 dB at 17.5 GHz and the effective bandwidth can cover the frequency range of 12.0-15.5 GHz with the thickness of 1.5 mm. Furthermore, an ultrawide effective bandwidth of 15.3 GHz can be achieved with the integrated thickness of 1.0-5.0 mm. Such a performance is superior to those of many reported Fe₃O₄/Fe composites, and a comparative analysis manifests that good microwave absorption of F-350 is also benefited from its unique 3D architecture.