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Carbonyl and olefin hydrosilylation mediated by an air-stable phosphorus(<scp>iii</scp>) dication under mild conditions
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References
2019
Year
Organic Material ChemistryChemical EngineeringEngineeringMild ConditionsOrganic ChemistryOrganometallic CatalysisCatalysisChemistryPhosphoreneOlefin HydrosilylationAsymmetric CatalysisAir-stable PhosphorusSynthetic ChemistryBiomolecular Engineering
The readily-accessible, air-stable Lewis acid [(terpy)PPh][B(C6F5)4]21 is shown to mediate the hydrosilylation of aldehydes, ketones, and olefins. The utility and mechanism of these hydrosilylations are considered.
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