Chemical Communications · 2019 · 55 citations · 18 references
Natural SciencesChemical EngineeringChemistryBiocatalysisEnergy MaterialsReaction EngineeringPhotocatalysisPhotoelectrochemical MaterialsQuantum DotsRedox ChemistryRedox EnzymesRedox-active MaterialsElectron ShuttlesElectron Transfer RatesPhotocatalytic MaterialsPhotocatalytic NanomaterialsRedox MediatorsSemiconductor PhotocatalysisSemiconductor PhotocatalystsSemiconductor Quantum Dots
A series of viologen related redox mediators of varying reduction potential has been characterized and their utility as electron shuttles between CdSe quantum dots and hydrogenase enzyme has been demonstrated. Tuning the mediator LUMO energy optimizes the performance of this hybrid photocatalytic system by balancing electron transfer rates of the shuttle.
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Charge Transfer Dynamics from Photoexcited Semiconductor Quantum Dots
Haiming Zhu, Ye Yang, Kaifeng Wu et al. · Annual Review of Physical Chemistry · 2016 · 222 citations · Full text
Natural Sciences, Chemistry, Physics +17