Publication | Open Access
An unprecedented {Ni<sub>14</sub>SiW<sub>9</sub>} hybrid polyoxometalate with high photocatalytic hydrogen evolution activity
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Citations
22
References
2019
Year
Materials ScienceInorganic ChemistryUnique Polyoxometalate ComplexVisible Light IrradiationPhotochemistryStable CompoundEngineeringPhotoredox ProcessInorganic PhotochemistrySynthetic PhotochemistryPhotocatalysisCatalysisHybrid PolyoxometalateChemistryHydrogenPhotoelectrocatalysisHybrid MaterialsPhotoelectrochemistry
A unique polyoxometalate complex made up of a tetradecanuclear nickel bisphosphonate cluster capping a {SiW9} unit has been characterized. This stable compound exhibits a high hydrogen evolution reaction photocatalytic activity under visible light irradiation via a reductive quenching mechanism.
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