Room temperature phosphorescent triarylborane functionalized iridium complexes

Abstract

We report a series of room temperature phosphorescent compounds 1-6 composed of triarylborane (TAB) and cyclometallated iridium complexes. The optical characteristics such as energy of transition and luminescence quantum yield of these compounds can be conveniently fine-tuned by judiciously varying the cyclometallating ligand and the spacer between boron and iridium centers. Compounds 1-6 exhibit bright phosphorescence with the emission color ranging from green to red under a N2 atmosphere. A maximum quantum yield of 0.95 was observed for complex 2. Complexes 1-6 exhibit a rare type of dual emission from singlet and triplet excited states under ambient conditions. The experimental observations are well supported by the theoretical calculations.