Electrochromism of fast photochromic radical complexes forming light-unresponsive stable colored radical cation

Abstract

We demonstrated the electrochromism of photochromic radical complexes containing triaryl imidazole: fast photoswitchable pentaarylbiimidazole (PABI) and the phenoxyl-imidazolyl radical complex (PIC). Cyclic voltammetry and spectroelectrochemistry revealed that PABI and PIC generate the highly stable radical cation by one-electron oxidation accompanied by a color change from colorless to green. The stability of the radical cation is strongly affected by the dihedral angle between the imidazole ring and the phenyl ring at the 2-position of the imidazole ring.