Thio-click reaction of 2-deoxy-<i>exo</i>-glycals towards new glycomimetics: stereoselective synthesis of <i>C</i>-2-deoxy-<scp>d</scp>-glycopyranosyl compounds

Abstract

Photoinitiated addition of thiols to 2-deoxy-<italic>exo</italic>-glycals obtained from <italic>endo</italic>-glycals of <sc>d</sc>-<italic>arabino</italic>, <sc>d</sc>-<italic>lyxo</italic>, <sc>d</sc>-<italic>erythro</italic> and <sc>d</sc>-<italic>threo</italic> configurations resulted in highly regio- and stereoselective formation of glycosylmethyl sulfide type glycomimetics.