¹³C NMR Shifts as an Indicator of U–C Bond Covalency in Uranium(VI) Acetylide Complexes: An Experimental and Computational Study

Abstract

A series of uranium(VI)-acetylide complexes of the general formula U^VI(O)(C≡C-C₆H₄-R)[N(SiMe₃)₂]₃, with variation of the para substituent (R = NMe₂, OMe, Me, Ph, H, Cl) on the aryl(acetylide) ring, was prepared. These compounds were analyzed by ¹³C NMR spectroscopy, which showed that the acetylide carbon bound to the uranium(VI) center, U- C≡C-Ar, was shifted strongly downfield, with δ(¹³C) values ranging from 392.1 to 409.7 ppm for Cl and NMe₂ substituted complexes, respectively. These extreme high-frequency ¹³C resonances are attributed to large negative paramagnetic (σ^para) and relativistic spin-orbit (σ^SO) shielding contributions, associated with extensive U(5f) and C(2s) orbital contributions to the U-C bonding in title complexes. The trend in the ¹³C chemical shift of the terminal acetylide carbon is opposite that observed in the series of parent (aryl)acetylenes, due to shielding effects of the para substituent. The ¹³C chemical shifts of the acetylide carbon instead correlate with DFT computed U-C bond lengths and corresponding QTAIM delocalization indices or Wiberg bond orders. SQUID magnetic susceptibility measurements were indicative of the Van Vleck temperature independent paramagnetism (TIP) of the uranium(VI) complexes, suggesting a magnetic field-induced mixing of the singlet ground-state (f⁰) of the U(VI) ion with low-lying (thermally inaccessible) paramagnetic excited states (involved also in the perturbation-theoretical treatment of the unusually large paramagnetic and SO contributions to the ¹³C shifts). Thus, together with reported data, we demonstrate that the sensitive ¹³C NMR shifts serve as a direct, simple, and accessible measure of uranium(VI)-carbon bond covalency.