Eu³⁺-Postdoped UIO-66-Type Metal–Organic Framework as a Luminescent Sensor for Hg²⁺ Detection in Aqueous Media

Abstract

Because of its extreme toxicity, the determination of Hg²⁺ in aqueous solution is an important subject for human health and environmental monitoring. In this study, a novel UIO-66-type metal-organic framework (MOF) doped with Eu³⁺ (isophthalic acid and 2,6-pyridinedicarboxylic acid and zirconium chloride served as the organic connectors and metal precursor, respectively) was prepared by a hydrothermal method and postsynthetic modification. The obtained lanthanide MOFs exhibited good photothermal and fluorescence stability in aqueous solution. As a luminescent probe, dispersions of the material can specifically recognize Hg²⁺ in many ions and have a detection limit of 8.26 nM. This novel lanthanide MOF shows great potential applications for biosensing, imaging, environmental analysis, and so on.