Precise control of single unit monomer radical addition with a bulky tertiary methacrylate monomer toward sequence-defined oligo- or poly(methacrylate)s <i>via</i> the iterative process

Abstract

Iterative single unit monomer radical addition with a bulky tertiary methacrylate monomer, adamantyl and isopropyl pendant methacrylate (IPAMA), under ATRP conditions was studied in detail toward the syntheses of sequence-defined oligo- or poly(methacrylate)s in higher yields.