Recyclable Au/SiO₂-Shell/Fe₃O₄-Core Catalyst for the Reduction of Nitro Aromatic Compounds in Aqueous Solution

Abstract

Highly stable gold nanoparticles immobilized on the surface of amine-functionalized nanocomposite microspheres possessing a magnetite (Fe₃O₄) nanoparticle core and a silica (SiO₂) shell (Au/SiO₂-shell/Fe₃O₄-core) were prepared. These gold nanocomposite catalysts were tested for 4-nitrophenol (4-NP) and 2-nitroaniline (2-NA) reduction in aqueous solution in the temperature range 293-323 K and in the presence of aqueous NaBH₄ reducing agent. The magnetically recyclable gold catalyst showed high stability (∼3 months), efficient recyclability (up to 10 cycles), and high activity (∼100% conversion within 225 s, ∼700 ppm 4-NP or 2-NA). The pseudo-first-order apparent reaction rate constants (<i>k</i>) of 4-NP and 2-NA reduction were 7.5 × 10^-3 and 4.1 × 10^-3 s^-1, respectively, and with an apparent catalytic activity of 4.48 × 10^-8 kmol/(m³ s).