Entropy‐Driven Mechanochemical Synthesis of Polymetallic Zeolitic Imidazolate Frameworks for CO₂ Fixation

Abstract

High-entropy materials refer to a kind of materials in which five or more metal species were incorporated deliberately into a single lattice with random occupancy. Up to now, such a concept has been only restricted to hard materials, such as high-entropy alloys and ceramics. Herein we report the synthesis of hybrid high-entropy materials, polymetallic zeolitic imidazolate framework (also named as high-entropy zeolitic imidazolate framework, HE-ZIF), via entropy-driven room-temperature mechanochemistry. HE-ZIF contains five metals including Zn^II , Co^II , Cd^II , Ni^II , and Cu^II which are dispersed in the ZIF structure randomly. Moreover, HE-ZIF shows enhanced catalytic conversion of CO₂ into carbonate compared with ZIF-8 presumably a result of the synergistic effect of the five metal ions as Lewis acid in epoxide activation.