Publication | Open Access
Cationic magnesium hydride [MgH]<sup>+</sup> stabilized by an NNNN-type macrocycle
32
Citations
65
References
2019
Year
A magnesium hydride cation [(L)MgH]<sup>+</sup> supported by a macrocyclic ligand (L = Me<sub>4</sub>TACD; 1,4,7,10-tetramethyl-1,4,7,10-tetraazacyclododecane) has been prepared by partial protonolysis of a mixed amide hydride [(L)MgH<sub>2</sub>Mg{N(SiMe<sub>3</sub>)<sub>2</sub>}<sub>2</sub>] and shown to undergo a variety of reactions with unsaturated substrates, including pyridine.
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