ACS Applied Materials & Interfaces · 2019 · 658 citations · 63 references
Natural SciencesMaterials EngineeringMaterials ScienceFunctional MaterialsMaterials ChemistryNanomaterialsMicrowave MaterialsPolymer FoamsShielding DesignShielding MaterialsAbsorption EfficiencyElectromagnetic Shielding MaterialsFoamsInterfacial PolarizationInternal ReflectionLightweight Shielding MaterialsPorous StructuresShielding Efficiency
Lightweight absorption-dominated electromagnetic interference (EMI) shielding materials are more attractive than conventional reflection-dominated counterparts because they minimize the twice pollution of the reflected electromagnetic (EM) wave. Here, porous Ti2CTx MXene/poly(vinyl alcohol) composite foams constructed by few-layered Ti2CTx (f-Ti2CTx) MXene and poly(vinyl alcohol) (PVA) are fabricated via a facile freeze-drying method. As superior EMI shielding materials, their calculated specific shielding effectiveness reaches up to 5136 dB cm2 g–1 with an ultralow filler content of only 0.15 vol % and reflection effectiveness (SER) of less than 2 dB, representing the excellent absorption-dominated shielding performance. Contrast experiment reveals that the good impedance matching derived from the multiple porous structures, internal reflection, and polarization effect (dipole and interfacial polarization) plays a synergistic role in the improved absorption efficiency and superior EMI shielding performance. Consequently, this work provides a promising MXene-based EMI shielding candidate with lightweight and high strength features.
63