Publication | Closed Access
Photoredox Defluorinative Alkylation of 1‐Trifluoromethyl Alkenes and 1,3‐Butadienes with 1,4‐Dihydropyridines as Alkylation Reagents
50
Citations
48
References
2019
Year
High YieldsChemical EngineeringDerivativesVisible Light IrradiationPhotochemistryEngineeringPhotoredox ProcessRadical (Chemistry)Fluorous SynthesisAlkylation ReagentsOrganic ChemistryPhotoredox Defluorinative AlkylationSynthetic PhotochemistryChemistrySequential C−cHalogenation
Abstract A radical defluorinative alkylation method of 1‐trifluoromethyl alkenes and 1,3‐butadienes with 4‐alkyl‐1,4‐dihydropyridines under visible light irradiation is presented. Various alkylated 1,1‐difluoroalkenes and 1,1‐difluorodienes were obtained in moderate to high yields through a sequential C−C and C−F bond cleavage process.
| Year | Citations | |
|---|---|---|
Page 1
Page 1