<i>In Operando</i> Synchrotron Diffraction and <i>in Operando</i> X-ray Absorption Spectroscopy Investigations of Orthorhombic V₂O₅ Nanowires as Cathode Materials for Mg-Ion Batteries

Abstract

Orthorhombic V2O5 nanowires were successfully synthesized via a hydrothermal method. A cell-configuration system was built utilizing V2O5 as the cathode and 1 M Mg(ClO4)2 electrolyte within acetonitrile, together with MgxMo6S8 (x ≈ 2) as the anode to investigate the structural evolution and oxidation state and local structural changes of V2O5. The V2O5 nanowires deliver an initial discharge/charge capacity of 103 mAh g–1/110 mAh g–1 and the highest discharge capacity of 130 mAh g–1 in the sixth cycle at C/20 rate in the cell-configuration system. In operando synchrotron diffraction and in operando X-ray absorption spectroscopy together with ex situ Raman and X-ray photoelectron spectroscopy reveal the reversibility of magnesium insertion/extraction and provide information on the crystal structure evolution and changes of the oxidation states during cycling.