Cobalt–Tannin‐Framework‐Derived Amorphous Co−P/Co−N−C on N, P Co‐Doped Porous Carbon with Abundant Active Moieties for Efficient Oxygen Reactions and Water Splitting

Abstract

It remains a tremendous challenge to develop a low-cost, earth-abundant, and efficient catalyst with multifunctional activities for the hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Herein, a facile and scalable avenue was developed to prepare amorphous Co-P/Co-N-C supported on N, P co-doped porous carbon (Co-P/Co-N-C/NPC) with a large specific surface area (1462.9 m² g^-1 ) and abundant reactive sites including Co-P, Co-N and NPC. The prepared electrocatalyst exhibits outstanding catalytic performance for HER (η=234 mV at 10 mA cm^-2 ), OER (η=374 mV at 10 mA cm^-2 ), and ORR (E_1/2 =0.89 V, vs. reversible hydrogen electrode). Benefiting from the excellent HER performance and outstanding OER activity, the Co-P/Co-N-C/NPC delivers a current density of 10 mA cm^-2 for overall water splitting at a cell voltage of 1.59 V, which is comparable with the IrO₂ -Pt/C couple electrode.