Electrochemical‐Conditioning‐Free and Water‐Resistant Hybrid AlCl₃/MgCl₂/Mg(TFSI)₂ Electrolytes for Rechargeable Magnesium Batteries

Abstract

Abstract Rechargeable magnesium batteries are a promising alternative to Li‐based energy storage because of their abundant and inexpensive components. The high sensitivity and reactivity of the organic Mg 2+ electrolyte makes their development challenging. Herein, we develop a new hybrid electrolyte, based on three simple inorganic salts of MgCl 2 , AlCl 3 , and Mg(TFSI) 2 . The electrolyte exhibits unprecedented electrochemical performance for reversible deposition and stripping of Mg, with Coulombic efficiency up to 97 %, overpotential down to 0.10 V, good stability especially for aluminum and stainless‐steel current collectors. It maintained its activity even after introducing 2000 ppm water and it could be prepared from impure chemicals. A full cell with the hybrid electrolyte and Mg foil as anode, Mo 6 S 8 as cathode gave a specific capacity of 98 mAh g −1 and maintained 94 % capacity after 100 cycles at a rate of 0.20 C, indicating the good compatibility of the hybrid electrolyte.