Chemical Communications · 2019 · 105 citations · 30 references
Materials ScienceInorganic ChemistryEngineeringProton-conducting MofsExcellent Water StabilityCovalent Bonded FrameworkHigh Proton ConductionPhysical ChemistryNew Metal-organic FrameworkChemistryMetal-organic PolyhedronMetal-organic FrameworksFunctional MaterialsElectrochemistryOrganic-inorganic Hybrid Material
A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10-2 S cm-1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs.
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