Gas Sensing with Iridium Oxide Nanoparticle Decorated Carbon Nanotubes

Abstract

The properties of multi-wall carbon nanotubes decorated with iridium oxide nanoparticles (IrO_x-MWCNTs) are studied to detect harmful gases such as nitrogen dioxide and ammonia. IrO_x nanoparticles were synthetized using a two-step method, based on a hydrolysis and acid condensation growth mechanism. The metal oxide nanoparticles obtained were employed for decorating the sidewalls of carbon nanotubes. Iridium-oxide nanoparticle decorated carbon nanotube material showed higher and more stable responses towards NH₃ and NO₂ than bare carbon nanotubes under different experimental conditions, establishing the optimal operating temperatures and estimating the limits of detection and quantification. Furthermore, the nanomaterials employed were studied using different morphological and compositional characterization techniques and a gas sensing mechanism is proposed.