The First 2D Hybrid Perovskite Ferroelectric Showing Broadband White‐Light Emission with High Color Rendering Index

Abstract

Abstract Luminescent ferroelectrics have attracted considerable attention in terms of integrated photoelectronic devices, most of which are focused on the multicomponent systems of rare‐earth doping ferroelectric ceramics. However, bulk ferroelectricity with coexistence of strong white‐light emission, especially in the single‐component system, remains quite rare. Here, a new organic–inorganic hybrid ferroelectric of (C 4 H 9 NH 3 ) 2 PbCl 4 ( 1 ) is reported, adopting a 2D layered perovskite architecture, which exhibits an unprecedented coexistence of notable ferroelectricity and intrinsic white‐light emission. Decent above‐room‐temperature spontaneous polarization of ≈2.1 µC cm −2 is confirmed for 1 . Particularly, it also exhibits brilliant broadband white‐light emission with a high color‐rendering‐index up to 86 under UV excitation. Structural analyses indicate that ferroelectricity of 1 originates from molecular reorientation of dynamic organic cations, as well as significant structural distortion of PbCl 6 octahedra that also contribute to its white‐light emission. This work paves an avenue to design new hybrid ferroelectrics for multifunctional application in the photoelectronic field.