Publication | Closed Access
Electrochemical Three‐Component 1,2‐Aminosulfonylation of Alkenes: Entry to 2‐sulfonylethan‐1‐amines
55
Citations
54
References
2018
Year
Reactivity DifferentiationChemical EngineeringEngineeringOrganic ElectrochemistryNatural SciencesDiversity-oriented SynthesisElectrosynthesisOrganometallic ElectrochemistryAdditive Redox CatalystsOrganic ChemistryElectrochemical Three‐component 1,2‐AminosulfonylationCatalysisChemistryAlkene AminosulfonylationElectrochemistry
Abstract A new electrochemical intermolecular 1,2‐aminosulfonylation of alkenes with sulfinates and amines is achieved by utilizing balanced three‐component interactions and reactivity differentiation. This strategy can be applicable to a wide range of amines, including primary and secondary amines, thus enabling alkene aminosulfonylation for producing diverse functionalized 2‐sulfonylethan‐1‐amines without the need of additive redox catalysts, metal catalysts and chemical oxidants. magnified image
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