Manganese(<scp>iii</scp>)-mediated selective phosphorylation of enamides: direct synthesis of β-phosphoryl enamides

Abstract

Mn(<sc>iii</sc>)-Mediated radical oxidative selective phosphorylation of<italic>N</italic>-styrylamides to afford β-phosphoryl enamides, which could be easily transformed to β-amino phosphonic acids, is described.