Chemical Communications · 2018 · 27 citations · 16 references
Natural SciencesChemistryPhysical ChemistrySupramolecular ChemistryCoordination ChemistryHost-guest ChemistryLigand BindingMetal-ligand BondingSelf-assemblyTransition Metal ComplexesCage AssemblyCalixarene Cage CompoundsCoordination Self-assemblyGuest EquilibriaMetal-organic Supramolecular AssembliesMolecular Cage FormationSelf-assembly In Host-guest Systems
The tetra-α isomer of a super aryl-extended tetra-pyridyl calix[4]pyrrole self-assembles into a mono-metallic Pd(ii)-cage featuring two different and converging polar binding sites. Mono- and di-topic polar guests are bound reversibly in the cage. A mechanism for guest exchange in the cage complexes is proposed.
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Coordination Assemblies from a Pd(II)-Cornered Square Complex
Makoto Fujita, Masahide Tominaga, Akiko Hori et al. · Accounts of Chemical Research · 2005 · 2K citations