Concepedia

Intermolecular oxidative radical fluoroalkylfluorosulfonylation of unactivated alkenes with (fluoroalkyl)trimethylsilane, silver fluoride, sulfur dioxide and <i>N</i>-fluorobenzenesulfonimide

Qiongzhen Lin, Yongan Liu, Zhiwei Xiao, Liping Zheng, Xiumiao Zhou, Yong Guo, Qing‐Yun Chen, Changge Zheng, Chao Liu

Organic Chemistry Frontiers · 2018 · 55 citations · 47 references

DOI

Concepts

Abstract

Reaction of unactivated alkenes affords various fluoroalkyl-containing alkyl sulfonyl fluorides with good functional group tolerance under mild conditions.

References

47

The Many Roles for Fluorine in Medicinal Chemistry

William K. Hagmann · Journal of Medicinal Chemistry · 2008 · 3.6K citations · Full text

, , +5

Sulfur(VI) Fluoride Exchange (SuFEx): Another Good Reaction for Click Chemistry

Jiajia Dong, Larissa B. Krasnova, M. G. Finn et al. · Angewandte Chemie International Edition · 2014 · 1.4K citations

, , +7

Fine Design of Photoredox Systems for Catalytic Fluoromethylation of Carbon–Carbon Multiple Bonds

Takashi Koike, Munetaka Akita · Accounts of Chemical Research · 2016 · 547 citations · Full text

, , +15

Sulfonyl fluorides as privileged warheads in chemical biology

Arjun Narayanan, Lyn H. Jones · Chemical Science · 2015 · 543 citations · Full text

, , +5

Synthetic methods and reactions. 141. Fluoride-induced trifluoromethylation of carbonyl compounds with trifluoromethyltrimethylsilane (TMS-CF3). A trifluoromethide equivalent

G. K. Surya Prakash, Ramesh Krishnamurti, George A. Olah · Journal of the American Chemical Society · 1989 · 529 citations

, , +4