Publication | Closed Access
Au(<scp>i</scp>)-Catalyzed hydroarylation of alkenes with <i>N</i>,<i>N</i>-dialkylanilines: a dual gold catalysis concept
26
Citations
77
References
2018
Year
EngineeringAlkene MetathesisNatural SciencesDiversity-oriented SynthesisMarkovnikov ProductsOrganic ChemistryOrganometallic CatalysisCatalysisHomogeneous CatalysisChemistryComplete SelectivityFull ConversionMolecular CatalysisSynthetic ChemistryBiomolecular Engineering
In the present work, we report the efficiency of the commercially available [(PPh<sub>3</sub>)AuCl] complex in combination with a set of potassium salts to catalyze the hydroarylation of a broad variety of alkenes using <italic>N</italic>,<italic>N</italic>-dialkylanilines, leading to full conversion and complete selectivity toward the Markovnikov products.
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