A ZnCl<sub>2</sub> water-in-salt electrolyte for a reversible Zn metal anode

Chong Zhang, John Holoubek, Xianyong Wu, Aigerim Daniyar, Liangdong Zhu, Cheng Chen, Daniel P. Leonard, Ismael A. Rodríguez‐Pérez, Jia‐Xing Jiang, Chong Fang,

Chemical Communications · 2018 · 736 citations · 17 references

Concepts

Abstract

We report a low-cost water-in-salt electrolyte, of 30 m ZnCl2, which enables a dendrite-free Zn metal anode to possess a high coulombic efficiency (CE). In asymmetric Zn‖Zn cells with a limited mass of plated Zn as the working electrode, the ZnCl2 WiSE improves the average CE of the Zn anode to 95.4% from 73.2% in 5 m ZnCl2.

References

17