Chemical Communications · 2018 · 736 citations · 17 references
Natural SciencesChemical EngineeringMaterials ScienceElectrochemical EngineeringElectrochemistryInorganic ChemistryAnode MaterialsElectrochemical CellsElectrode MaterialsElectrode-electrolyte InterfacesElectrolyte MaterialsElectrolyte SolutionsAnode DesignAnode PerformanceCoulombic EfficiencyElectrolyte EngineeringNanostructured AnodesWater-in-salt Electrolytes
We report a low-cost water-in-salt electrolyte, of 30 m ZnCl2, which enables a dendrite-free Zn metal anode to possess a high coulombic efficiency (CE). In asymmetric Zn‖Zn cells with a limited mass of plated Zn as the working electrode, the ZnCl2 WiSE improves the average CE of the Zn anode to 95.4% from 73.2% in 5 m ZnCl2.
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