Concepedia

Unsymmetrical β-diketiminate magnesium(<scp>i</scp>) complexes: syntheses and application in catalytic hydroboration of alkyne, nitrile and carbonyl compounds

Jia Li, Man Luo, Xingchao Sheng, Haiming Hua, Weiwei Yao, Sumod A. Pullarkat, Li Xu, Mengtao Ma

Organic Chemistry Frontiers · 2018 · 102 citations · 27 references

DOI

Concepts

Abstract

A series of unsymmetrical magnesium(<sc>i</sc>) complexes have been synthesized and used as highly active pre-catalysts for various hydroboration reactions.

References

27

Stable Magnesium(I) Compounds with Mg-Mg Bonds

S.P. Green, Cameron Jones, Andreas Stasch · Science · 2007 · 802 citations

, , +12

β‐Diketiminate‐Stabilized Magnesium(I) Dimers and Magnesium(II) Hydride Complexes: Synthesis, Characterization, Adduct Formation, and Reactivity Studies

S.J. Bonyhady, Cameron Jones, Sharanappa Nembenna et al. · Chemistry - A European Journal · 2009 · 449 citations

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Magnesium-catalysed hydroboration of aldehydes and ketones

Merle Arrowsmith, Terrance J. Hadlington, Michael S. Hill et al. · Chemical Communications · 2012 · 242 citations

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Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents

Andreas Stasch, Cameron Jones · Dalton Transactions · 2011 · 235 citations

, , +10

An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

Zhi Yang, Mingdong Zhong, Xiaoli Ma et al. · Journal of the American Chemical Society · 2016 · 220 citations

, , +13