Concepedia

Publication | Closed Access

Application of Hantzsch Ester and Meyer Nitrile in Radical Alkynylation Reactions

36

Citations

52

References

2018

Year

Abstract

The first example of constructing a C<sub>sp3</sub>-C<sub>sp</sub> bond with substituted Hantzsch ester and Meyer nitrile is reported. When benziodoxole-activated alkyne was applied as the alkynyl donor, products containing C<sub>sp3</sub>-C<sub>sp</sub> bonds involving primary, secondary, and tertiary carbon centers were achieved in up to 97% yields. K<sub>2</sub>S<sub>2</sub>O<sub>8</sub> was the optimum radical initiator in this reaction.

References

YearCitations

Page 1