Electro-generation of hydrogen peroxide using a graphite cathode from exhausted batteries: study of influential parameters on electro-Fenton process

Abstract

In this work, the study of hydrogen peroxide (H₂O₂) electro-generation using graphite from exhausted batteries (Gr-Bat) was conducted. Linear sweep voltammetry and electrolysis experiments were carried out in a single compartment electrochemical cell. Study of the possibility to use this electrode revealed that it presents, as vitreous carbon (VC) electrode, a reduction of oxygen with two successive waves (bi-electronic reduction). The first wave corresponds to the reduction of O₂ to H₂O₂, while the second one corresponds to the reduction of H₂O₂ to H₂O. The cathodic potentials for electro-generation of H₂O₂ appeared at -600 and -700 mV vs. Ag/AgCl for Gr-Bat and VC electrodes, respectively. Subsequently, electrolysis experiments were conducted by imposing the potentials required for H₂O₂ formation. The effect of several operating parameters on H₂O₂ production, such as the nature and concentration of the electrolyte, the pH, the presence of ferrous ions and O₂ injection were studied using Gr-Bat and VC electrodes, respectively. For both electrodes, the acidic medium was more favorable for H₂O₂ electro-generation. The oxygen injection in solution promoted an increase of H₂O₂ concentration, but its effect was more pronounced in the case of VC electrode. Application for crystal violet degradation by electro-Fenton revealed that Gr-Bat had the best purification performance. A removal rate of 73.18% was obtained with Gr-Bat electrode against 62.27% with VC electrode for an electrolysis time of 120 min. This study has demonstrated the possibility of recycling Gr-Bat by using them as cathode materials in the electro-Fenton process.