ATRA-like alkylation–peroxidation of alkenes with trichloromethyl derivatives by the combination of <i>t</i>BuOOH and NEt₃

Abstract

This protocol provides a unique and innovative approach to the construction of α-<italic>tert</italic>-butylperoxy-β-dichloromethyl alkanes, employing CHCl₃ as an alkylating reagent to provide a –CHCl₂ group, and TBHP as an oxidant to provide an α-^tBuOO group.