A Neutral η⁵‐Aminoborole Complex of Germanium(II)

Abstract

The synthesis of two η⁵ -aminoborole complexes of germanium(II) from the reaction of a germole dianion with aminoboron dichlorides is reported. This reaction constitutes a remarkable example of a germole-to-borole transformation. The two aminoborole complexes of germanium(II) were fully characterized by multinuclear NMR spectroscopy, IR spectroscopy, HRMS, and, in one case, by X-ray crystallography. The results of quantum-mechanical calculations favor the electronic structure of a half-sandwich complex of Ge^II over an ionic representation with a germanium dication stabilized by an aromatic aminoborole dianion.