Observation of Carbodicarbene Ligand Redox Noninnocence in Highly Oxidized Iron Complexes

Abstract

To probe the possibility that carbodicarbenes (CDCs) are redox active ligands, all four members of the redox series [Fe(1)₂ ]ⁿ⁺ (n=2-5) were synthesized, where 1 is a neutral tridentate CDC. Through a combination of spectroscopy and DFT calculations, the electronic structure of the pentacation is shown to be [Fe^III (1^.+ )₂ ]⁵⁺ (S= <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:mn>1</mml:mn> <mml:mo>/</mml:mo> <mml:mn>2</mml:mn></mml:mrow> </mml:math> ). That of [Fe(1)₂ ]⁴⁺ is more ambiguous, but it has significant contributions from the open-shell singlet [Fe^III (1)(1^.+ )]⁴⁺ (S=0). The observed spin states derive from antiferromagnetic coupling of their constituent low-spin iron(III) centres and cation radical ligands. This marks the first time redox activity has been observed for carbones and expands the diverse chemical behaviour known for these ligands.