Concepedia

Stibine-protected Au<sub>13</sub>nanoclusters: syntheses, properties and facile conversion to GSH-protected Au<sub>25</sub>nanocluster

Ying‐Zhou Li, Rakesh Ganguly, Kar Yiu Hong, Yongxin Li, Malcolm E. Tessensohn, Richard D. Webster, Weng Kee Leong

Chemical Science · 2018 · 49 citations · 82 references

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Concepts

Abstract

Monostibine-protected ionic Au<sub>13</sub>nanoclusters, namely, [Au<sub>13</sub>(L)<sub>8</sub>(Cl)<sub>4</sub>][Cl] (L = SbPh<sub>3</sub>,<bold>2a</bold>·Cl; Sb(<italic>p</italic>-tolyl)<sub>3</sub>,<bold>2b</bold>·Cl) were prepared by the direct reduction of Au(L)Cl with NaBH<sub>4</sub>in dichloromethane.

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