ChemCatChem · 2018 · 45 citations · 62 references
Natural SciencesChemical EngineeringChemistryCatalysisNanomaterialsReaction EngineeringCatalyst DesignCatalytic MaterialsCatalytic MechanismsCatalytic Reaction EngineeringNanocatalysisSupported CatalystsDehydrogenationDehydrogenation CatalysisDehydrogenation ReactionsElectron DensityLewis AcidityMesoporous MaterialsMesoporous NanomaterialsNanostructured Catalysts
Abstract Pd−Ni bimetallic nanoparticles (BMNPs) encapsulated in MIL‐100(Fe) (Pd‐Ni@MIL‐100(Fe) was fabricated and employed as an efficient catalyst for the reversible dehydrogenation/hydrogenation of N‐Heterocycles derivatives in water under mild conditions. Excellent catalytic performance for both reactions endows Pd‐Ni@MIL‐100(Fe) great potential value in organic chemistry. Alloying Pd with Ni can enhance the catalytic performance due to the bimetallic synergy. Both Lewis acidity and ordered mesoporous structure of MIL‐100(Fe) are beneficial to the performance of the catalyst owing to its stabilization of BMNPs, reduction of the electron density of Pd atoms and enhancement of substrates adsorption capacity.
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A facile synthesis of UiO-66, UiO-67 and their derivatives
Michael J. Katz, Zachary J. Brown, Yamil J. Colón et al. · Chemical Communications · 2013 · 1.7K citations