Violet‐blue emission property of the cerium‐ion doped CaHfO₃: Doping and temperature dependence

Abstract

We investigated the emission property of perovskite CaHfO₃ polycrystals with various concentrations of cerium ion (Ce³⁺ ). With a wide range of UV photoexcitation, we observed a strong emission near 430 nm which should originate from 5d-4f transitions in the Ce³⁺ ions. Combining these emission spectra with the photoluminescence excitation spectra, we estimated the Stokes shift to be 6700 cm^-1 , irrespective of the Ce³⁺ ion doping concentration. We found that the violet-blue emissions in Ce³⁺ ions showed non-trivial temperature dependence in their peak position and intensity. We found interesting low-temperature behavior of the violet-blue emission, which might be attributed to the thermal lattice effect in CaHfO₃ . We also discussed our results with those of the similar materials, perovskite zirconates. Our systematic studies provide useful information on the host material CaHfO₃ for a future study on the violet-blue emission of Ce³⁺ ions.