A NaSO<sub>2</sub>CF<sub>3</sub>/NaBrO<sub>3</sub>-mediated bromotrifluoromethylation of enyne <i>via</i> free-radical cascade processes - Concepedia

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A NaSO<sub>2</sub>CF<sub>3</sub>/NaBrO<sub>3</sub>-mediated bromotrifluoromethylation of enyne <i>via</i> free-radical cascade processes

38

Citations

69

References

2018

Year

Xiaojie Shang, Dong Liu, Zhong‐Quan Liu

Organic Chemistry Frontiers

HalogenationCross-coupling ReactionEngineeringNatural SciencesMolecular BiologyOrganic ChemistryStep-economic AccessSix-membered HeterocyclesChemistryHeterocycle ChemistryRadical BromotrifluoromethylationBiomolecular Engineering

Abstract

A NaBrO<sub>3</sub>-induced radical bromotrifluoromethylation of enynes with NaSO<sub>2</sub>CF<sub>3</sub> was developed. This method allows a transition-metal free, highly selective and step-economic access to diverse bromotrifluoromethylated five- and six-membered heterocycles.

References

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