Removal of mercury(II) from contaminated water by gold-functionalised Fe₃O₄magnetic nanoparticles

Abstract

Fe₃O₄ nanoparticles were prepared by co-precipitation of Fe²⁺ and Fe³⁺ and then modified with Au to produce an effective adsorbent (Fe₃O₄/Au) for aqueous Hg(II) in contaminated water. Rietveld refinement on the XRD pattern confirmed that the Fe₃O₄/Au was synthesised. Mössbauer spectra exhibited broad and asymmetric resonance lines with two sextets which can be assigned to tetrahedral Fe³⁺; and octahedral Fe³⁺/Fe²⁺. The quantitative analysis of magnetite confirms that the sample shows around 3 wt.% Au and 97 wt.% partially oxidised Fe₃O₄. High surface area: 121 m² g^-1, average pore sizes: 6.3 nm and pore volume: 1.64 cm³ g^-1. The kinetics data were better fitted with a pseudo-second-order and Dubinin-Radushkevich isotherm suggests the Hg(II) adsorption onto Fe₃O₄/Au nanoparticles was mainly by chemical adsorption forming complex with the Au metal immobilised on Fe₃O₄ surfaces. Adsorption capacity of 79.59 mg g^-1. Ionic strength and co-existing ions had a slight influence on the adsorption capacity.