Highly Productive Propane Dehydrogenation Catalyst Using Silica-Supported Ga–Pt Nanoparticles Generated from Single-Sites

Abstract

The development of more effective alkane dehydrogenation catalysts is a key technological challenge for the production of olefins from shale gas, an abundant source of light hydrocarbons. Surface organometallic chemistry provides an original approach to generate nanometric Ga-Pt bimetallic particles supported on partially dehydroxylated silica containing gallium single-sites, which displays high activity, selectivity, and stability in propane dehydrogenation. This catalyst was prepared via sequential grafting of a platinum precursor onto silica possessing site-isolated gallium sites followed by H₂ reduction. Monitoring generation of the reduced species, Ga^δ+Pt⁰/SiO₂, via in situ X-ray absorption spectroscopy reveals formation of a Ga _xPt (0.5 < x < 0.9) alloy with a fraction of gallium remaining as isolated sites. This bimetallic material exhibits catalytic performance that far surpasses each of the individual components and other reported Ga-Pt based catalysts; this is attributed to the highly dispersed Ga _xPt alloyed structure on a support with low Brønsted acidity containing gallium single-sites.