Concepedia

Photochemical activation of SF<sub>6</sub> by N-heterocyclic carbenes to provide a deoxyfluorinating reagent

Pooja Tomar, Thomas Braun, Erhard Kemnitz

Chemical Communications · 2018 · 65 citations · 36 references

DOI

Concepts

Abstract

A photochemical activation of SF<sub>6</sub> provides access to difluoroimidazolidine derivatives, which can serve as intermediates to shuttle fluorides to alcohols by deoxyfluorination.

References

36

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Moritz F. Kuehnel, Dieter Lentz, Thomas Braun · Angewandte Chemie International Edition · 2013 · 421 citations

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Deoxyfluorination of Phenols

Pingping Tang, Weike Wang, Tobias Ritter · Journal of the American Chemical Society · 2011 · 272 citations · Full text

, , +2

The decomposition products of sulfur hexafluoride (SF6): Reviews of environmental and health risk analysis

Wen‐Tien Tsai · Journal of Fluorine Chemistry · 2007 · 190 citations

, , +13

The Evolution of Pd<sup>0</sup>/Pd<sup>II</sup>-Catalyzed Aromatic Fluorination

Aaron C. Sather, Stephen L. Buchwald · Accounts of Chemical Research · 2016 · 169 citations · Full text

, , +15