Converting detrimental HF in electrolytes into a highly fluorinated interphase on cathodes

Changchun Ye, Wenqiang Tu, Limei Yin, Qinfeng Zheng, Cun Wang, Yaotang Zhong, Yuegang Zhang, Qiming Huang, Kang Xu, Weishan Li

Journal of Materials Chemistry A · 2018 · 180 citations · 59 references

Concepts

Abstract

A silane molecule with an unsaturated functionality effectively scavenges harmful hydrogen fluoride from the electrolyte and forms a complex, which experiences preferential oxidation and eventually delivers the fluorine species to the interphase that protects cathodes of high energy density batteries.

References

59