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Copper-modulated bismuth nanocrystals alter the formate formation pathway to achieve highly selective CO<sub>2</sub> electroreduction
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2018
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EngineeringCu-element DopingSolid-state ChemistryNanoheterogeneous CatalysisChemistryElectronic StructureChemical EngineeringQuantum MaterialsFormate Formation PathwayNanostructure SynthesisCopper-modulated Bismuth NanocrystalsMaterials ScienceInorganic ChemistryPhysicsNanotechnologyAtomic PhysicsBi AtomsQuantum ChemistryNanocrystalline MaterialSolid-state PhysicElectrochemistryElectronic MaterialsNanomaterialsNatural SciencesLocal Electronic EnvironmentApplied PhysicsCondensed Matter Physics
The local electronic environment of Bi atoms is modulated by Cu-element doping, guaranteeing efficient HCOOH formation <italic>via</italic> an OCHO* intermediate.
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