Grating-like SERS substrate with tunable gaps based on nanorough Ag nanoislands/moth wing scale arrays for quantitative detection of cypermethrin

Abstract

M) to 4-aminothiophenol (4-ATP), outstanding signal uniformity (the relative standard deviations were less than 15%) and superior identification performance in the quantitative detection of pesticide cypermethrin. The three-dimensional finite-difference time-domain (3D-FDTD) method simulated the spatial distribution of the electric field intensity in the substrates with different morphologies, showing a potential strong enhancement of Raman signals in sub-10 nm gaps between two adjacent Ag nanoislands of different layers. These prominent SERS properties of novel Ag/MW SERS-active substrates suggest their potential value in rapid on-side biological and chemical sensing. Meanwhile, the highly-ordered nanoarrays of moth wings provide a new idea for the preparation of regular biomimetic nanomaterials.