Concepedia

Photoinduced fragmentation-rearrangement sequence of cycloketoxime esters

Binlin Zhao, Cheng Chen, Jiahang Lv, Zexian Li, Yu Yuan, Zhuangzhi Shi

Organic Chemistry Frontiers · 2018 · 60 citations · 46 references

DOI

Concepts

Abstract

A novel rearrangement of cycloketoxime esters to cyano-containing benzoates beyond the traditional Beckmann and Neber rearrangement process has been established in the presence of photocatalysis catalysis.

References

46

Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

John D. Nguyen, Erica M. D’Amato, Jagan M. R. Narayanam et al. · Nature Chemistry · 2012 · 760 citations

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Catalytic alkylation of remote C–H bonds enabled by proton-coupled electron transfer

Gilbert J. Choi, Qilei Zhu, David C. Miller et al. · Nature · 2016 · 754 citations · Full text

, , +9

Amide-directed photoredox-catalysed C–C bond formation at unactivated sp3 C–H bonds

John C. K. Chu, Tomislav Rovis · Nature · 2016 · 557 citations · Full text

, , +5

“Cut and Sew” Transformations via Transition-Metal-Catalyzed Carbon–Carbon Bond Activation

Penghao Chen, Brent A. Billett, Tatsuhiro Tsukamoto et al. · ACS Catalysis · 2017 · 468 citations · Full text

, , +10

Visible‐Light‐Mediated Generation of Nitrogen‐Centered Radicals: Metal‐Free Hydroimination and Iminohydroxylation Cyclization Reactions

Jacob Davies, Samuel G. Booth, Stéphanie Essafi et al. · Angewandte Chemie International Edition · 2015 · 411 citations · Full text