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Synthesis of cassane-type diterpenes from abietane compounds: the first synthesis of taepeenin F
12
Citations
42
References
2018
Year
Bioorganic ChemistryEngineeringTaepeenin FOrganic ChemistryChemistryChemical DerivativePharmaceutical ChemistryBiosynthesisAbietic AcidFormyl GroupDerivativesBiochemistryCassane-type DiterpenesPharmacologyNatural Product SynthesisNatural SciencesAbietane CompoundsDerivative (Chemistry)Synthetic Chemistry
The first synthesis of taepeenin F from abietic acid is reported, utilizing as the key step the <italic>ipso</italic>-substitution of the isopropyl group of a dehydroabietane derivative by a formyl group, after treatment with Cl<sub>2</sub>CHOMe and AlCl<sub>3</sub>.
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