New Journal of Chemistry · 2018 · 65 citations · 46 references
Natural SciencesChemistryPhysicsCondensed Matter PhysicsMagnetic MaterialsPhysical ChemistryCluster ChemistryCluster CompoundsCurie TemperatureMagnetic SusceptibilityMagnetism Of Inorganic CompoundsPhase TransitionsCluster SynthesisLanthanide Single-molecule MagnetsMagnetic Properties Of ClustersMagnetic RefrigerationMagnetic Refrigeration MaterialsStructural Characterization Of ClustersTransition Metal Clusters
A series of butterfly-shaped LnIII4 clusters were successfully synthesized. Magnetic studies show that the Gd<sub>4</sub> cluster displays magnetic refrigeration (Δ<italic>S</italic><sub>m</sub> = 18.85 J kg<sup>−1</sup> K<sup>−1</sup> for Δ<italic>H</italic> = 7.0 T at 2.5 K), while the Dy<sub>4</sub> cluster shows SMMs behavior with Δ<italic>E</italic>/k<sub>B</sub> of 79.15 K and <italic>τ</italic><sub>0</sub> of 5.82 × 10<sup>−8</sup> s.
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Transition-metal-based magnetic refrigerants for room-temperature applications
O. Tegus, E. Brück, K.H.J. Buschow et al. · Nature · 2002 · 2.6K citations
Natural Sciences, Materials Engineering, Materials Science +14
You‐Song Ding, Nicholas F. Chilton, Richard E. P. Winpenny et al. · Angewandte Chemie International Edition · 2016 · 916 citations · Full text
Natural Sciences, Chemistry, Physics +17