Publication | Closed Access
DDQ‐Promoted Allylic C−H Phosphorylation of 1,3‐Diarylpropenes
22
Citations
73
References
2018
Year
Room TemperatureCross-coupling ReactionEngineeringConvenient RouteNatural SciencesDiversity-oriented SynthesisOrganic ChemistryOrganometallic CatalysisChemistryAllylic C−h PhosphorylationDdq‐promoted Cross‐dehydrogenative CouplingAsymmetric CatalysisEnantioselective SynthesisBiomolecular Engineering
Abstract An efficient allylic C−H phosphorylation has been achieved through the DDQ‐promoted cross‐dehydrogenative coupling of 1,3‐diarylpropenes with P(O)H compounds at room temperature. This method provides a convenient route to allylphosphonates in up to 97% yield with good functional group compatibility. magnified image
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