Flexible porphyrin cages and nanorings

Abstract

We have reviewed recent advances in the synthesis of porphyrin cages and nanorings with flexible links, as well as their applications in host–guest chemistry and catalysis. Template-directed strategies have greatly facilitated the synthesis of porphyrin cages and nanorings with high complexities. Meanwhile, the unique features of flexible porphyrin cages and nanorings having a good balance between rigidity and flexibility make them especially suitable to encapsulate fullerenes, multipyridyl compounds and other guests.