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Synthesis of hydrophobic MIL-53(Al) nanoparticles in low molecular weight alcohols: systematic investigation of solvent effects

Jan Warfsmann, Begüm Tokay, Neil R. Champness

CrystEngComm · 2018 · 43 citations · 51 references

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Concepts

Abstract

Employing methanol as a reaction solvent when preparing MIL-53(Al) leads to a highly porous MOF without the requirement of an energy-consuming activation process.

References

51

A Chemically Functionalizable Nanoporous Material [Cu <sub>3</sub> (TMA) <sub>2</sub> (H <sub>2</sub> O) <sub>3</sub> ] <sub> <i>n</i> </sub>

S.S.-Y. Chui, S.M.F. Lo, J.P.H. Charmant et al. · Science · 1999 · 6K citations

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Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging

Patricia Horcajada, Tamim Chalati, Christian Serre et al. · Nature Materials · 2009 · 4.2K citations · Full text

, , +13

A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon Hydration

Thierry Loiseau, Christian Serre, Clarisse Huguenard et al. · Chemistry - A European Journal · 2004 · 2.1K citations

, , +16

Water harvesting from air with metal-organic frameworks powered by natural sunlight

Hyunho Kim, Sungwoo Yang, Sameer R. Rao et al. · Science · 2017 · 1.8K citations · Full text

, , +11

Hydrogen adsorption in the nanoporous metal-benzenedicarboxylate M(OH)(O<sub>2</sub>C–C<sub>6</sub>H<sub>4</sub>–CO<sub>2</sub>) (M = Al<sup>3+</sup>, Cr<sup>3+</sup>), MIL-53

Gérard Férey, M. Latroche, Christian Serre et al. · Chemical Communications · 2003 · 718 citations

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