eCommons (Cornell University) · 2012 · 161 citations · 7 references
A novel class of amine-supported sorbents based on amine-bridged mesoporous polysilsesquioxane was developed via a simple one-pot sol-gel process. The new sorbent allows the incorporation of a large amount of active groups without sacrificing surface area or pore volume available for CO2 capture, leading to a CO2 capture capacity of 3.2 mmol g?1 under simulated flue gas conditions. The sorbent is readily regenerated at 100?C and exhibits good stability over repetitive adsorption-desorption cycling. ? 2011 Society of Chemical Industry and John Wiley & Sons, Ltd
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